Line a ceramic or glass container with aluminium foil (or use an aluminium pan). Fill it up with boiling water and and add one tablespoon of baking soda and one tablespoon of salt. Drop in your silver pieces and make sure they touch both the foil and each other. Then just sit back and watch it work. When they are bright and shiny again (takes just a minute), fish them out, rinse them off and dry with a clean soft cloth.
Some of my napkin-rings were really black and not everything went away. To finish those last black parts I mixed baking soda with a little bit of water to a paste and just rubbed it for a few seconds. Now they're all shiny. Really easy and cheap and no chemicals!
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